Verses with the word pained in the Old Testament (4 verses):

Psalms 55:4
My heart is sore pained within me: and the terrors of death are fallen upon me.

Isaiah 23:5
As at the report concerning Egypt, so shall they be sorely pained at the report of Tyre.

Jeremiah 4:19
My bowels, my bowels! I am pained at my very heart; my heart maketh a noise in me; I cannot hold my peace, because thou hast heard, O my soul, the sound of the trumpet, the alarm of war.

Joel 2:6
Before their face the people shall be much pained: all faces shall gather blackness.