Verses with the word emerald in the Old Testament (3 verses):

Exodus 28:18
And the second row shall be an emerald, a sapphire, and a diamond.

Exodus 39:11
And the second row, an emerald, a sapphire, and a diamond.

Ezekiel 28:13
Thou hast been in Eden the garden of God; every precious stone was thy covering, the sardius, topaz, and the diamond, the beryl, the onyx, and the jasper, the sapphire, the emerald, and the carbuncle, and gold: the workmanship of thy tabrets and of thy pipes was prepared in thee in the day that thou wast created.